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Abstract
Journal of Sedimentary Research, Section
A: Sedimentary Petrology and Processes
Vol. 65A (1995)No.
1. (January), Pages 170-177
Geochemistry of Carbonate Cements in Surficial Alluvial Conglomerates and
their Paleoclimatic Implications, Sultanate of Oman
Stephen J. Burns, Albert Matter
ABSTRACT
Early diagenetic carbonate cements are a common feature of Quaternary alluvial
conglomerates in Oman. Cements are formed in the vadose and, more commonly,
phreatic zones from near-surface groundwaters. In drainage areas underlain
by the Semail Ophiolite, groundwaters have Mg2+/Ca2+
ratios greater than two, and cements are often dolomite or high-magnesium
calcite in addition to low-magnesium calcite. In drainage areas underlain
by limestone, groundwaters have Mg2+/Ca2+ ratios
of around one or less and cement mineralogy is nearly always low-magnesium
calcite. The oxygen and carbon stable isotopic ratios of the cements vary
widely, from -10.6
to + 3.0
PDB and from -10.0
to + 0.7
PDB, respectively. Cement d18O values
principally reflect variation in rainfall d18
over a time scale of several thousand years. Rainfall and cement d18O
values probably are inversely correlated with the mount of rainfall, which
is related to the frequency and intensity of the Indian Ocean monsoon.
Thus, cement d18O is potentially
a proxy indicator of relative rainfall and monsoon activity. For each of
three sampling areas, d13C is positively
correlated to d18O. Cement d13C
values are also related to rainfall amount because rainfall controls the
plant population. Greater plant respiration of isotopically depleted CO2
to shallow groundwaters and burial of organic material in conglomerate
deposits results in lower cement d13C
values compared to periods of lesser plant activity.
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