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Abstract

Uliasz-Bochenczyk, A., E. Mokrzycki, M. Mazurkiewicz, Z. Piotrowski, and R. Pomykala, 2009, Carbon dioxide utilization within ash-water suspensions deposited in underground coal mines, in M. Grobe, J. C. Pashin, and R. L. Dodge, eds., Carbon dioxide sequestration in geological media—State of the science: AAPG Studies in Geology 59, p. 655663.

DOI:10.1306/13171268St593401

Copyright copy2009 by The American Association of Petroleum Geologists.

Carbon Dioxide Utilization within Ash-Water Suspensions Deposited in Underground Coal Mines

Alicja Uliasz-Bochenczyk,1 Eugeniusz Mokrzycki,2 Maciej Mazurkiewicz,3 Zbigniew Piotrowski,4 Radoslaw Pomykala5

1Mineral and Energy Economy Research Institute of the Polish Academy of Science, Cracow, Poland
2Mineral and Energy Economy Research Institute of the Polish Academy of Science, Cracow, Poland
3AGH University of Science and Technology, Faculty of Mining and Geoengineering, Department of Mining Area Ecology, Cracow, Poland
4AGH University of Science and Technology, Faculty of Mining and Geoengineering, Department of Mining Area Ecology, Cracow, Poland
5AGH University of Science and Technology, Faculty of Mining and Geoengineering, Department of Mining Area Ecology, Cracow, Poland

ABSTRACT

The most significant source of CO2 emissions in Poland is the power industry, which is based on conventional fuels: hard coal and lignite. During electricity and heat production, significant amounts of combustion by-products are formed, mainly fly ash. Fly ash is applied in underground mining in Poland as ash-water suspensions that are used to fill underground excavations, as well as for many other high-tech mining procedures. In Poland, 10,653,800 tons of fly ash have been used by the industry, and of those, 5,233,700 tons or 49%, have been used in coal mines.

Fly ash used to bind CO2 should possess high CaO content, thus causing direct reaction with water. High CaO concentrations are also found in fly ash with exhaust gas desulfurization products (sim12% CaO). Low CaO concentrations are found in fly ash originating from hard-coal combustion (sim1% CaO).

The amount of absorbed CO2 and its influence on the properties of suspensions depend, among other things, on the kind of ash, the ratio of ash to water, and the intensity with which the suspensions are mixed with CO2. The largest amount of CO2 was absorbed into the shaken suspensions containing fly ash from lignite combustion after 25 days of seasoning (8.8 g CO2/100 g).

The idea is to use CO2 based on its binding by the process of mineral carbonation within water-ash suspensions being deposited in underground mines. The latter might be regarded as a particular form of geological CO2 sequestration.

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