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The AAPG/Datapages Combined Publications Database
Journal of Sedimentary Research (SEPM)
Abstract
Research Articles:
Carbonate
Diagenesis
Diagenetic Cycling of Nutrients in Seafloor Sediments and the
Carbonate
–Silica Balance in a Paleozoic Cool-Water
Carbonate
System, Sverdrup Basin, Canadian Arctic Archipelago
Abstract
Seafloor processes are often destructive of biogenic remains, while at the same time promoting growth of authigenic minerals such as hematite, fluorapatite, glauconite, and chalcedony. Middle to Late Permian sedimentary rocks in the Sverdrup Basin are cool-water marine sandstones, shales, limestones, and cherts, rich in
carbonate
and siliceous biotic components. The authigenic minerals hematite, fluorapatite, glauconite, and chalcedony are abundant, from the interactions of nutrient elements (silica, phosphorus, and iron), with
carbonate
and siliceous biotas in ramp environments of variable energy and sediment accumulation rate. These authigenic phases represent, in part, faunas that are no longer preserved, and should not be viewed simply as diagenetic products.
Early
middle Permian siliciclastic rocks (the Assistance Formation) contain
carbonate
heterozoan biotas with widespread siderite and hematite, and local void-filling phosphate, deposited under moderate sediment accumulation rates. Sponge spicules were dissolved unless encased in hematite or siderite, and incorporated in silica cement. In contrast, more slowly deposited younger middle Permian inboard cherty limestones (the lower Trold Fiord Formation) underwent frequent physical and biological reworking, resulting in dissolution of biogenic silica and precipitation of glauconite, and
carbonate
fluorapatite. Sediment reworking also excavated and produced rounded glauconite and phosphate clasts; much of the glauconite was then oxidized to hematite on the seafloor. Again, unless encased in phosphate, sponge spicules were dissolved and the silica precipitated as glauconite or chalcedony. Coeval deeper-water phosphatic cherty limestones (the Degerbols Formation) do, however, contain sponge spiculites. Reduced sediment reworking led to retention of silica in pore fluids and slowed dissolution of sponge spicules, resulting in local preservation of sponge spiculite facies.
Late Permian organic-rich cherts (the Lindstrom Formation), with prolific siliceous sponges and a less plentiful
carbonate
biota, accumulated relatively slowly. Sponge spicules were preserved and
carbonate
biota partially dissolved in these organic-rich deposits, implying that the biota had to be overwhelmingly dominated by siliceous components to overcome ambient silica undersaturation in pore fluids.
Each succession has a distinct composition depending upon the rate of sediment accumulation, the original benthic biota, and the nature and abundance of silica, phosphate, and iron in seawater at any given time. These characteristics controlled the formation of authigenic minerals and the preservation or dissolution of
carbonate
and silica biotas.
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