ABSTRACT

Upper Cretaceous shallow-marine sediments from Vega Island, Antarctica, contain five major authigenic phases; glauconite, pyrite, a zeolite mineral of the clinoptilolite-heulandite group, chlorite, and calcite. The framework sediment composition changes from quartzose at the base of the measured succession to volcaniclastic at the top. The petrogenesis of individual samples reflects the local controls on diagenesis of depositional environment and sediment composition, combined with the effects of burial to no more than 1 km. Calcite cements are the most abundant precipitates. Marine carbonate cements include acicular and other fringing cements that commonly are present within bioclasts. Early-burial micritic to sparry calcite cements include both concretionary and nonconcretionary for s. Burial calcites occlude residual porosity, replace detrital grains and form veins with fibrous and cone-in-cone textures. The stable-isotope composition of the carbonate cements is very variable, with ¹⁸O ranging from 0.60 to - 19.93 PDB and ¹³C of - 1.33 to - 28.09 PDB. The stable-isotope data reflect the initial conditions of mineral precipitation in oxic and anoxic marine pore waters, together with the effects of subsequent fluid/rock interaction t rough both recrystallization and cementation. The latest precipitates, thought to have been formed during over pressuring, define a vertical field for burial calcite on an isotope cross plot, suggesting that late fluids responsible for cementation and alteration of earlier precipitates had negative ¹⁸O and contained carbon with variable ¹³C. The oxygen values are compatible with either influx of high-latitude meteoric water or intense fluid-rock interaction with reactive volcanic detritus, or a combination of the two processes. The very variable carbon signatures probably reflect dissolution of bioclasts and earlier diagenetic precipitates. Only by identifyi g possible end-member compositions for both early and late diagenetic precipitates can most of the isotopic data be interpreted correctly.