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The AAPG/Datapages Combined Publications Database
Journal of Sedimentary Research (SEPM)
Abstract
Hydrothermal Dolomitization and Recrystallization of Dolomite Breccias from the Miocene Monterey Formation, Tepusquet Area, California
Mitchell J. Malone (1) (*), Paul A. Baker (1), Stephen J. Burns (2)
ABSTRACT
Recrystallization of matrix dolomites is indicated by the uniformly negative d18O compositions (x = -7.1 d), low Sr contents (x = 230 ppm), low Na contents (x = 364 ppm), contracted unit cells (x: a = 4.812 A, c = 16.058 A), high degree of cation order, high Mg content (x = 46.1 mol% MgCO3) as compared to most Monterey dolomites, and increasing 87Sr/86Sr ratios with decreasing Sr content. Vein dolomites have large variation in stoichiometry (41.7-49.0 mol% MgCO3), Sr content (124-414 ppm), unit-cell dimensions (a: 4.806-4.829 A, c: 16.013-16.178 A), and cation order (Ca site occupancy: 0.73-0.93, g site: 0.68-0.94). Recrystallization of some vein dolomites is indicated by the covariance of mol% MgCO3 with Sr, d18O, cation order, and unit-cell parameters. The covariance of d18O with mol% MgCO3 is the inverse of the trend expected for the recrystallization of dolomite during burial diagenesis, possibly because of recrystallization during uplift.
Vein dolomites have higher 87Sr/86Sr values
than matrix dolomites. The least radiogenic matrix dolomites (the least
recrystallized as inferred from the d18O
composition) have 87Sr/86Sr apparent ages (13.0 and
15.5 Ma ± 0.3) that agree well with the previously mapped age of
the brecciated unit. The more recrystallized matrix dolomites have higher
87Sr/86Sr
ratios (apparent ages too young for the lower Monterey Formation), thus
recording the evolution of Sr isotopic composition of the pore fluid. The
close chemical similarity of the vein dolomites and the most recrystallized
matrix dolomites, the episodic association between hydrocarbons and the
ve n dolomites, and the recrystallization trends in the matrix dolomites,
all indicate that evolved formation waters were the source of the hydrothermal
fluids that precipitated the vein dolomites.
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