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* Definitions and Mechanisms Peter J. Ortoleva Indiana University Bloomington, Indiana, U.S.A. * ABSTRACT A classification scheme for compartments and seals is introduced and physico-chemical processes underlying their genesis and evolution are suggested. The sedimentary basin is viewed as a chemical reactor of epic scale constantly being driven out of equilibrium. As a result, it sustains a variety of important compartmentation and sealing phenomena. Practical implications of this can be obtained by building a comprehensive model accounting for operating physico-chemical processes and then developing computer codes to simulate it. We argue that this is feasible and can contribute greatly to the development of exploration, production, and resource assessment strategies. Diagenesis deep in a sedimentary basin involves a number of strongly coupled reaction, transport, and mechanical (RTM) processes. When a coupled RTM system is driven sufficiently far-from-equilibrium, it can become organized in space or time in ways that have no direct relation to patterns imposed at the basin boundary or through sedimentary input. Rather, these patterns organize themselves. Our results to date suggest that many aspects of compartment and seal genesis and dynamics appear to be a manifestation of this far-from-equilibrium dynamic. If sedimentation was very slow, then all fluids could escape and rock at depth would be porosity-free. But beyond some critical subsidence and burial rate, fluid can get trapped in compartments for appreciable times. This is because relatively uncompacted rock finds itself at appreciable depth. This rock is therefore far-from-equilibrium--a large free energy difference exists between the uncompacted and the compacted system due to the overburden stress. A most dramatic manifestation of far-from-equilibrium conditions occurs when the system develops periodic or other oscillatory variations in space or time. A sequence of episodic fluid releases from an overpressurizing compartment can occur via a cycle of fracture generation and healing. Also, alternating layers of contrasting texture or mineralogy can develop to produce textural banding that has been found to be at the root of a number of pressure seals. We set forth the general point of view
that a basin is a far-from-equilibrium system capable of sustaining a variety
of compartmentation phenomena. Compartments, banded seals, and episodic
fluid migration and other phenomena key to petroleum exploration, production,
and resource assessment are found to be consequences of the far-from-equilibrium
basin dynamic.
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