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Milliken, K. L., R. J. Day-Stirrat, P. K. Papazis, and C. Dohse, 2012, Carbonate lithologies of the Mississippian Barnett Shale, Fort Worth Basin, Texas, in J. A. Breyer, ed., Shale reservoirs—Giant resources for the 21st century: AAPG Memoir 97, p. 290–321.

DOI:10.1306/13321473M97252

Copyright copy2012 by The American Association of Petroleum Geologists.

Carbonate Lithologies of the Mississippian Barnett Shale, Fort Worth Basin, Texas

Kitty L. Milliken,1 Ruarri J. Day-Stirrat,2 Petro K. Papazis,3 Christian Dohse4

1Bureau of Economic Geology, Jackson School of Geosciences, The University of Texas at Austin, Austin, Texas, U.S.A.
2Bureau of Economic Geology, Jackson School of Geosciences, The University of Texas at Austin, Austin, Texas, U.S.A.
3Chevron Canada Resources, Calgary, Alberta, Canada
4Mango Properties, LLP, Corpus Christi, Texas, U.S.A.

ACKNOWLEDGMENTS

This study was supported by a grant from the Geology Foundation of the Jackson School of Geosciences. The Foundation also provided scholarships to Petro K. Papazis. Christian Dohse was supported by a grant for undergraduate research from the University Cooperative Society. We thank Bob Loucks (Bureau of Economic Geology) and Mike Cameron (Devon Energy Corporation) for their assistance in providing access to cores. Charlotte Sullivan kindly included us on a field trip that introduced us to the Barnett Shale outcrops of the northern Llano uplift. Leo Lynch (deceased) generously provided the x-ray powder diffraction data. Special thanks to Ignacio Pujana (The University of Texas at Dallas) who set KLM straight on identification of the radiolaria and radiolaria fragments in her CL images. Mike Cameron, Bob Loucks, Jurgen Schieber, Joe Macquaker, and Bob Folk are friends of mudrocks who have spent time with us in the field, in the core warehouse, and at the microscope, helping us to learn about the Barnett Shale. We are most grateful to have had their counsel. The manuscript benefited from reviews by Christopher Swezey and Stephen Ruppel. This chapter is published with the permission of the Director, Bureau of Economic Geology.

ABSTRACT

Carbonate-rich lithologies of the gas-producing Upper Mississippian Barnett Shale, Fort Worth Basin, Texas, are diverse and include lithologies with carbonate components that are primarily authigenic, as well as those that have carbonate components dominated by skeletal debris and other allochems such as peloids and intraclasts. Compositionally, carbonate-bearing lithologies of the Barnett Shale (including the informal unit known as the Forestburg Limestone) can be viewed as mixtures of authigenic or allochemical carbonate and siliciclastic sediment derived mostly from outside the basin. With the exception of the Forestburg Limestone, these varied carbonate lithologies dominate only in local zones, at the scale of a hand specimen or thin section, and do not constitute a volumetrically significant part of the gas-producing reservoir rock. Carbonate lithologies are significant, however, for clues they provide on environmental and early diagenetic conditions during accumulation of the Barnett Shale. Carbonate lithologies dominated by skeletal components contain distinct and impoverished marine faunas that are consistent with low oxygenation levels. The generally early timing of carbonate cement precipitation is supported by the reworking of diagenetic carbonate as silt- to sand-size intraclasts, sediment infilling of fractures in cemented beds and concretions, displacive fabrics, and highly random orientations of phyllosilicate grains within carbonate units. In some cases, detrital allochemical carbonates provided nucleation substrates for precipitation of highly displacive authigenic carbonate that was extensively reworked into microspar-size sediment particles. The elemental and isotopic chemistries of authigenic carbonates are consistent with near-sea-floor authigenesis driven by microbial cycling of organic carbon into carbonate minerals under generally reducing and low-temperature conditions.

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