Storage of carbon dioxide (CO₂) by precipitation of carbon-bearing minerals in geological formations is, on the long run, more stable and therefore much safer than direct storage or solution trapping. Among available options for CO₂ sequestration that are particularly attractive are those that offer additional economic benefits apart from the primary positive effect for the atmosphere (e.g., enhanced gas or oil recovery), such as the novel approach of storing dissolved CO₂ as calcite in managed geothermal aquifers.

Hydrogeothermal energy in Germany is mainly provided from deep sandstone aquifers by a so-called doublet installation consisting of one well for hot water production and one well for injection of the cooled water. When cold brines are enriched with CO₂ and injected into an anhydrite-bearing reservoir, this mineral dissolves. As a result, the water becomes enriched in calcium ions. Numerical simulations demonstrate that dissolved Ca and CO₂ react to form and precipitate calcium carbonate provided that alkaline buffering capacity is supplied from plagioclase in the reservoir rock or by surface water treatment with fly ashes. We show that anhydrite dissolution with the concurrent pore-space increase is important to balance pore-space reduction by precipitation of calcite and secondary silicates. Laboratory experiments prove the feasibility of transforming anhydrite into calcite and provide necessary kinetic input data for the modeling.

Suitable geothermal reservoirs exist, which contain sufficient anhydrite as matrix mineral and plagioclase for supplying alkalinity. Mass balance calculations performed with respect to the anhydrite and feldspar content show that, for an assumed operation time of 30 yr, the theoretical storage capacity is significant: millions of tons of CO₂ can be trapped as calcite in geological formations used by geothermal heating plants.