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The AAPG/Datapages Combined Publications Database

AAPG Bulletin

Abstract


Volume: 54 (1970)

Issue: 12. (December)

First Page: 2444

Last Page: 2447

Title: Evidence Against Oxidation of Hydrogen Sulfide by Sulfate Ions to Produce Elemental Sulfur in Salt Domes: GEOLOGICAL NOTES

Author(s): J. B. Davis (2), J. P. Stanley (2), H. C. Custard (2)

Abstract:

Oxidation of hydrogen sulfide to elemental sulfur by sulfate ions did not occur at 70°C in carefully controlled experiments. Such oxidation has been proposed as a means by which hydrogen sulfide is oxidized to sulfur in the subsurface, particularly in the environment of salt-dome sulfur deposits. However, thermodynamically, the reaction is unfavorable at neutral and alkaline pH, and would not occur to an appreciable extent given infinite time. An alternative oxidizing agent is dissolved oxygen of groundwater or seawater which tends to limit the depth at which deposits of native sulfur formed.

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